Synthesis and structural characterization of a novel dimolybdenum(I) compound with mixed‐tribridging ligands: [Bu4N][Mo2(μ‐SPh)2(μ‐Cl(CO6]

A novel mixed‐tribridged dimolybdenum(I) compound [Bn₄N][Mo₂(μ‐SPh)₂(μ‐Cl)(CO)₆] (1) has been synthesized from the reaction of Mo₂(CO)₃(SPh)₂ with BU₄NCl. Compound 1 was characterized by IR, UV‐Vis and ¹H, ¹³C, ⁹⁵Mo NMR spectroscopic analyses. The electrochemical behavior was measured by cyclic voltammetry, indicating a quasi‐reversible two‐electron transfer in one step. The crystal structure determined by X‐ray crystallography shows that 1 contains a [Mo₂(μ‐S)₂(μ‐Cl)]^? core with a planar Mo₂S₂unit and a Cl bridge. The Mo? Mo distance is 0.28709(7) nm, and the Mo‐Cl‐Mo angle is 66.44(4)°. A newface‐sharing bioctahedral structure is discussed.     

Global regularity for modified critical dissipative quasi-geostrophic equations

We consider the n-dimensional modified quasi-geostrophic (SQG) equations

t_∂θ + u . ∇θ + κΛαθ = 0,${\partial }_t\theta \hspace{0.17em}+\hspace{0.17em}u\hspace{0.17em}.\hspace{0.17em}\nabla \theta \hspace{0.17em}+\hspace{0.17em}\kappa {\Lambda }^{\alpha }\theta \hspace{0.17em}=\hspace{0.17em}0,$

u = Λα-1 R^⊥θ$u\hspace{0.17em}=\hspace{0.17em}{\Lambda }^{\alpha -1}\hspace{0.17em}{R}^{\perp }\theta$

with κ > 0, α ∈ (0,1] and θ₀ ∈ W1, ∞ (?ⁿ). In this paper, we establish a different proof for the global regularity of this system. The original proof was given by Constantin, Iyer, and Wu [5], who employed the approach of Besov space techniques to study the global existence and regularity of strong solutions to modified critical SQG equations for two dimensional case. The proof provided in this paper is based on the nonlinear maximum principle as well as the approach in Constantin and Vicol [2].     

Global classical solution of the Cauchy problem to 1D compressible Navier–Stokes equations with large initial data

In this paper, we prove that the 1D Cauchy problem of the compressible Navier–Stokes equations admits a unique global classical solution (ρ,u)$(\rho ,\mathrm{u})$ if the viscosity μ(ρ)=1+ρ^β$\mu (\rho )=1+{\rho }^{\beta }$ with β?0$\beta ?0$. The initial data can be arbitrarily large and may contain vacuum. Some new weighted estimates of the density and velocity are obtained when deriving higher order estimates of the solution.     

Remarks on partial regularity for suitable weak solutions of the incompressible magnetohydrodynamic equations

In this paper, we are concerned with the partial regularity for suitable weak solutions of the tri-dimensional magnetohydrodynamic equations. With the help of the De Giorgi iteration method, we obtain the results proved by He and Xin (C. He, Z. Xin, Partial regularity of suitable weak solutions to the incompressible magnetohydrodynamic equations, J. Funct. Anal. 227 (2005) 113–152), namely, the one dimensional parabolic Hausdorff measure of the possible singular points of the velocity field and the magnetic field is zero.     

新颖无限三股螺旋钴配位聚合物{[Co(4,4''''-bipyridine)(4,4''''azobispyridine)_2(NCS)_2]·H_2O}_n的合成、结构和性质的研究(英文)

0IntroductionThereisagreatcurrentinterestforthecrystalengineeringofcoordinationframeworks犤1,2犦,notonlybecauseoftheirpotentialapplicationsaszeolite-likematerialsinmolecularselection,ionexchange,andcatalysis,butalsobecauseoftheirintriguingvarietyofarchitecturesandnewtopologies.Uptonow,themostimportantdrivingforcesincrystalengineeringarecoordinationbondingandhydrogenbondinginteract-ion犤3～5犦.Theuniquedirectionality,strength,andcom-plementaryofnon-covalenthydrogenandcoordinatedbondingplayanimp…     

液晶显示器用衬垫料的扫描电镜图像

论述了液晶显示器 (LCD)用衬垫料的作用和性能要求。给出了液晶显示器用衬垫料的扫描电镜图像。该图像对观测衬垫料的粒径分布和控制液晶显示器的盒厚均匀程度 ,消除液晶显示器的底色差异具有一定的意义。实验所得图像为从事液晶显示器的工程技术人员提供了清晰的衬垫料图像 ,为排除衬垫料的不均匀因素所造成的液晶屏的质量问题提供了依据。     

A Novel Plasticizer for the Preparation of Thermoplastic Starch

TPS was a biodegradable material based on starch. Starch was an inexpensive and natural renewable polysaccharide, which was widely investigated as the substitute of petroleum-derived plastics. Native starch commonly existed in granule structure with about…     

荧光猝灭法测定痕量六价铬

基于六价铬与碘化钾反应生产了单质碘，碘可以使2′，7′－二氯荧光素（DCF）发生荧光猝来，从而间接测定六价铬。六价铬浓度在0．20－2．50μg/25ml范围内，荧光强度差值与六价铬浓度呈线性关系，线性回归方程△F=12．12 0．19，相关系数r=0.9993，检出限为0．10μg/ml。方法简便，灵敏度较高，已用于合成样中六价铬的测定。回收率在100％－103％，结果满意。